Telechelic PolymersCRC Press, 31.12.1988 - 416 sivua This first-of-its-kind publication reviews the most impor-tant literature on the synthesis, properties, and applications of telechelic polymers. Written by a group of internationally known ex-perts in the field, this text contains a review table which allows the reader to search for given polymers with given end groups. Over 1,250 references are listed, covering primary and review articles as well as patents. Chapters include the preparation of telechelics by stepwise polymerization, anionic polymerization, radical polymer-ization, cationic polymerization, ring-opening polymerization and controlled polymer degradation. Polyols for the polyurethane pro-duction are described, as well as halato-telechelic polymers. Also, a more theoretical contribution on the physical properties of net-works formed from telechelic polymers is provided. |
Sisältö
Introduction | 6 |
Use of a Chain Limitator | 19 |
Chemical Modification of EndGroups | 25 |
Ernest Marechal | 33 |
Chapter 4 | 61 |
Chapter 5 | 95 |
Chapter 6 | 115 |
Chapter 7 | 141 |
Chapter 8 | 163 |
Chapter 9 | 181 |
Chapter 10 | 229 |
Chapter 11 | 261 |
Chapter 12 | 289 |
Yleiset termit ja lausekkeet
a,w-dicarboxy acid addition AIBN alcohol alkoxide amine anhydride anionic polymerization Bayer bifunctional block copolymers Bull carbon carboxylate catalyst cationic CH₁ CH₂ CH3 CH3 chain ends Chem chemical chloride cleavage compounds concentration copolymerization cross-linking CTPs cyclic derived diisocyanate diol distribution double bond elastomers end-capped end-groups Equation ester ether ethylene oxide Figure formation formed functional groups glycol graft copolymers hydroxyl groups increase initiator ion pair ionic isocyanate Kennedy living polymer Macromolecules macromonomers Makromol methacrylate method molecular weight molecule monofunctional monomer nucleophilic obtained oligomers poly(ethylene polybutadiene polycondensation polyester polyether polyether polyols polymer chain polyols polystyrene polyurethane prepared propagation propylene oxide ratio reacted reactive reagent rigid foam Ring-Opening Polymerization rubber scission side reactions soluble solution solvent species starter structure styrene synthesis of telechelics telechelic polymers temperature Terminal Groups transfer triol U.S. Patent units unsaturated vinyl viscosity